https://signup.mailgun.com/new/signup
Please note: MailGun often requires to contact support to enable your account - a measure they have in place against abuse
Go to https://app.mailgun.com/app/domains/new and enter your domain, ideally a subdomain, e.g. mg.yourdomain.org
Then follow the steps provided to verify and configure your domain
MAILGUN_API_KEY
MAILGUN_DOMAIN
MAILGUN_SMTP_LOGIN
MAILGUN_SMTP_PASSWORD
MAILGUN_PUBLIC_KEY
(from https://app.mailgun.com/app/account/security)
See also Heroku